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Article #209: The Science of it All Part II

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Engine oil additives The problem? They can strip away more
Do they really work? than sludge or deposits. They can strip
That question has sparked controversy for away the boundary lubrication layer
years in the automotive and diesel provided by your motor oil. With that,
industries. Are the various engine oil you would be promoting increased
additives really just the modern metal-to-metal contact within your
automotive versions of "Snake Oil"? engine.
Many engine oil additives promise to "Miracle" Zinc?
reduce friction. The presence of friction Zinc dialkyldithiophosphate ("zinc") was
- metal on metal inside the engine's originally touted as the "miracle" engine
combustion chamber - generates intense oil additive, replacing Ptfe. As an
heat and often indicates the galling of engine oil additive it has been used in
metal parts and surfaces. In other words, many standard additive packages.
your engine is being gouged, scored or Zinc is advertised for extreme pressure,
gashed piece by piece over time. (See anti-wear engine protection. It is
test photos at reference below). particularly useful in high stress,
There are several major kinds of engine prolonged metal-to-metal conditions found
oil additives: in racing. But, for all of its fanfare,
1. Ptfe engine oil additives racing conditions are not what the vast
(Polytetrafluoroethylene, which is Teflon majority of motorists face.
TM). Your automobile should never face such
2. Engine oil additives containing stresses under normal, everyday driving
solvents and detergents, such as conditions. Interestingly enough, years
kerosene, naphthalene, xylene, acetone or ago oil companies reduced the amount of
isopropanol. zinc in standard engine oil packages
3. Engine oil additives containing zinc because of damage to catalytic converters
dialkyldithiophosphate ("zinc" for our and increased spark plug fouling.
purposes here). Furthermore, zinc is a hazardous
4. Engine oil products using the same substance. It has the capacity to inflict
additives used by oil manufacturers, only serious damage to your eyes. As an engine
in different amounts and combinations. oil additive, it really hasn't "lived up"
5. Other engine oil additives such as to its original high expectations. And as
chlorinated paraffins and molybdenum. a "miracle", you won't start a new
Ptfe religion with this one.
Polytetrafluoroethylene got off to a Same additives used by car manufacturers
rough start in its early career as an The oils from major oil companies
engine oil additive. The DuPont Chemical servicing the automotive, truck and bike
Corporation, its inventor, issued a now industries already come "loaded" with
famous statement which read: "Teflon is engine oil additives and work in
not useful as an ingredient in oil combinations, synergistically. Adding
additives or oils used for internal more of the same additive will not bring
combustion engines." added benefit.
By court action, DuPont was forced to Many things in the world of chemistry act
sell Ptfe to manufacturers of engine oil in such a way that more is definitely not
additives. To their credit, DuPont still better. Think of adding a hot pepper
maintains they have "no knowledge of any sauce to a mix. Some adds flavor. More
advantage gained through the use of PTFE can make for a memorable event.
in engine oil." Sulfur compounds, for example, are used
Why the controversy? Remember, this to protect your engine at lower engine
additive is a suspended solid. Imagine temperatures but coke out forming sludge
introducing an additive with solids which at higher temperatures. More will not
your oil filter is designed to remove. help your engine and can, in fact, do
So, your oil filter collects as much of actual harm.
the suspended solids as possible. The "Other" engine oil additives: More snake
result? Clogged oil filters and a marked oil
drop in oil pressure. Chlorinated paraffins have had some
Ah, but there's a "comeback" to that success as an engine oil additive. But,
critique. Manufacturers claim it is of there are severe drawbacks. With intense
sub-micron size, passing through engine heating, as in an internal combustion
oil filters. engine, the chlorinated paraffins release
That isn't the whole story. hydrochloric gases and acids.
I've spent nearly three decades working Chlorinated paraffins are thermally
to find chemical solutions to industrial unstable and above 200°C deteriorate,
problems. When you test chemicals, you generating strong acid radicals (hydrogen
must follow them through the whole cycle chloride, free chloride ions). These
of their use. radicals begin to attack metal surfaces,
Polytetrafluoroethylene expands radically forming chloride films of the metal.
in size when subjected to heat. It starts "Stress crack corrosion" in the metal
out "sub-micron", but you won't find any surfaces and corrosion of bearings,
guarantees that it will stay that size piston and valve trains can result.
when engine heats to normal operating Chlorinated Paraffins are known to be
temperatures. carcinogens, toxic to humans and to
Ptfe is often criticized for the oil aquatic environments. These substances
pressure drop accompanying its use. This accumulate, bringing effects that may be
again is probably due to the clogging of irreversible to man or environment.
oil filters. What is disturbing is that Molybdenum engine oil additives claim to
there are tests showing the presence of maintain or improve the antiwear
iron contamination in the oil due to antifriction properties of engine oil.
increased engine wear after its use. The problem is that they solidify and may
Maybe this one is best kept in your create clogged bypass filters, block oil
non-stick frying pan. galleries, reduced lubrication and add
Solvent and detergent engine oil engine surface wear.
additives: Outmoded? Frankly, none of these problems are
Engine oil additives designed to dissolve necessary. There is a much better
sludge and carbon deposits inside your solution to the engine oil additives
engine use solvents and detergents. They issue. It's no "miracle" either. It came
are usually naphthalene, xylene, acetone, straight out of the science and
isopropanol or kerosene in a standard successful use of decades of industrial
mineral base. manufacturing solutions.






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